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Updated: Jan 31, 2026

Facile Preparation of 4-Substituted Quinazoline Derivatives
Published on: February 15, 2016
A Facile Route to Nonlinear Optical Materials: Three-Site Aliovalent Substitution Involving One Cation and Two Anions
Jin Chen1,2, Chun-Li Hu1, Fei-Fei Mao1
1State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, P. R. China.
Abstract:
Two mixed-metal gallium iodate fluorides, namely, α- and β-Ba2 [GaF4 (IO3 )2 ](IO3 ) (1 and 2), have been designed by the aliovalent substitutions of α- and β-Ba2 [VO2 F2 (IO3 )2 ](IO3 ) (3 and 4) involving one cationic and two anionic sites. Both 1 and 2 display large second-harmonic generation responses (≈6×KH2 PO4 (KDP)), large energy band gaps (4.61 and 4.35 eV), wide transmittance ranges (≈0.27-12.5 μm), and high relevant laser-induced damage thresholds (29.7× and 28.3×AgGaS2 , respectively), which indicates that 1 and 2 are potential second-order nonlinear optical materials in the ultraviolet to mid-infrared. Our studies propose that three-site aliovalent substitution is a facile route for the discovery of good NLO materials.
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