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Guest Solvent-dependence of the Nanomechanical Response in Substituted Dihydropyrimidinone Crystals
Subhrajyoti Bhandary1, Gulshan Rani1, S R N Kiran Mangalampalli2
1Crystallography and Crystal Chemistry Laboratory, Department of Chemistry, Indian Institute of Science Education and Research Bhopal, Bhopal-By-Pass Road, Bhauri, Bhopal-, 462066, Madhya, Pradesh, India.
Abstract:
The nanomechanical responses of two crystalline phases of a dihydropyrimidine analogue (1) were similar irrespective of the presence (or absence) of the guest solvent. In contrast, the mechanical responses of two differently solvated forms of the second related (2) crystals were significantly different. These contrasting behaviors are rationalized in terms of intermolecular interactions and energy distributions.
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