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AIE active salicylaldehyde-based hydrazone: A novel single-molecule multianalyte (Al3+ or Cu2+) sensor in different
Zhi-Hong Xu1, Yuan Wang2, Yang Wang1
1Key Laboratory of Chemo/Biosensing and Detection, School of Chemistry and Chemical Engineering, Xuchang University, Xuchang 461000, PR China; College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, PR China.
Abstract:
A simple asymmetric hydrazone 1 based on salicylaldehyde was designed and prepared, and exhibited an evident aggregation-induced emission (AIE) at a long wavelength of 570 nm in aqueous medium. Probe 1 can selectively sense Al3+ in CH3OH solution through the chelation-enhanced fluorescence mechanism and also recognize Cu2+ via fluorescence quenching in H2O solution through the Cu2+-induced assembly of aggregates. In addition, the probe can be applied for detecting Cu2+ in biological samples.
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