Speciation analysis of chromium by carboxylic group functionalized mesoporous silica with inductively coupled plasma...

Carboxyl-group functionalized mesoporous silica (CFMS) prepared by one-pot co-condensation method was employed for the solid phase extraction (SPE) of chromium species for the first time. A new approach of SPE coupled to inductively coupled plasma mass spectrometry (ICP-MS) was thus established for the speciation of chromium in environmental water samples. The influences of pH, volume of sample, extraction time, amount of adsorbent, elution conditions, co-existing ions and adsorption capacity were investigated on adsorption or elution of chromium species. Cr(VI) was not retained on the CFMS material in the pH range of 1.0-9.0, while Cr(III) was quantitatively adsorbed at pH 5.0-9.0. The captured Cr(III) was enriched by using 1.5 mol L^-1 HNO₃ as elution solvent and detected by ICP-MS. Under the optimized SPE conditions, the maximum adsorption capacity of the CFMS for Cr(III) was 57.67 mg g^-1 and the enrichment factor was 25, with the detection limit (LOD) of 0.02 μg L^-1. The proposed protocol has been successfully applied to chromium speciation in rain, lake and river water samples, which exhibited a prospect in field separation and enrichment of chromium species in environmental waters.