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Published on: November 11, 2013
Moss-Derived Mesoporous Carbon as Bi-Functional Electrode Materials for Lithium⁻Sulfur Batteries and Supercapacitors
Wen Lei1, Haipeng Liu2, Junlei Xiao3
1The State Key Laboratory of Refractories and Metallurgy, and Institute of Advanced Materials and Nanotechnology, Wuhan University of Science and Technology, Wuhan 430081, China. leiwen@wust.edu.cn.
Abstract:
In this work, we reported a moss-derived biomass porous carbon (MPC) as a bi-functional electrode material for both the lithium⁻sulfur battery and the supercapacitor. The MPC was prepared from a high-temperature calcination procedure using the moss as the carbonaceous precursor. Using NaOH, the MPC was activated to give a mesoporous structure with a high specific surface area (1057.1 m² g-1) and large pore volume (0.72 cm³ g-1). When it was used as the cathode material in lithium⁻sulfur batteries, the MPC material realized a sulfur loading and exhibited a remarkably improved electrochemical performance, i.e., a high discharge capacity of 1070 mAh g-1 at 0.1 C. This activated MPC also worked well as a capacitive electrode in supercapacitors, demonstrating a high specific capacitance of 332 F g-1 (scan rate of 1.0 A g-1) and a high capacity retention > 97% in a long-term cycle of 1000 charge/discharges. This work demonstrated a facile method for the utilization of activated waste biomass material for future clean energy applications.
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