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Related Experiment Video

Updated: Jan 30, 2026

Protocol for Relative Hydrodynamic Assessment of Tri-leaflet Polymer Valves
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Revisiting the Stokes-Einstein relation without a hydrodynamic diameter.

Lorenzo Costigliola1, David M Heyes2, Thomas B Schrøder1

  • 1"Glass and Time," IMFUFA, Department of Science and Environment, Roskilde University, P.O. Box 260, DK-4000 Roskilde, Denmark.

The Journal of Chemical Physics
|January 17, 2019
PubMed
Summary
This summary is machine-generated.

The Stokes-Einstein relation breaks down at high temperatures for Lennard-Jones fluids. Reduced diffusion and viscosity are constant along isomorphs, enabling viscosity prediction from diffusion coefficients.

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Area of Science:

  • Thermodynamics
  • Fluid Dynamics
  • Statistical Mechanics

Background:

  • The Stokes-Einstein relation connects diffusion and viscosity in fluids.
  • Its applicability is limited, particularly at higher temperatures and densities.
  • Understanding these transport properties is crucial for characterizing fluid behavior.

Purpose of the Study:

  • To investigate the breakdown of the Stokes-Einstein relation in Lennard-Jones fluids.
  • To analyze diffusion coefficient and shear viscosity data across a wide temperature and density range.
  • To establish a predictive relationship between diffusion and viscosity.

Main Methods:

  • Analysis of diffusion coefficient and shear viscosity data for Lennard-Jones fluid.
  • Examination of data along isochores above critical density.
  • Evaluation of the Stokes-Einstein relation and isomorphs.

Main Results:

  • The Stokes-Einstein relation shows gradual breakdown at high temperatures.
  • Reduced diffusion coefficient and reduced viscosity are constant along isochores.
  • A functional relationship between reduced diffusion, reduced viscosity, and temperature/density scaling was identified.

Conclusions:

  • The breakdown of the Stokes-Einstein relation is linked to temperature-dependent scaling along isomorphs.
  • Viscosity can be accurately predicted from the diffusion coefficient in the studied thermodynamic region.
  • This work provides insights into the behavior of dense fluids.