Related Experiment Video
Updated: Jan 30, 2026

Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
Published on: August 12, 2013
Gel Polymer Electrolyte with High Li+ Transference Number Enhancing the Cycling Stability of Lithium Anodes
Yanan Wang1, Lixin Fu1, Liyi Shi1
1Research Center of Nanoscience and Nanotechnology , Shanghai University , Shanghai 200444 , China.
Abstract:
Lithium anodes suffer from severe safety problems in liquid electrolyte systems that result from an unstable Li plating/stripping process and Li dendrite growth, leading to rapid degradation of Li metal batteries. A polyethylene (PE)-supported gel polymer electrolyte (GPE) with excellent electrolyte uptake/retention capability was simply prepared in this paper by the construction of cross-linked polymer networks (PNs) on the surface of a poly(ethylenimine)-primed PE separator to stabilize the lithium anode. The highly delocalized negative charge of p-styrene sulfonate groups on PNs plays a role in regulating the Li+ and anion transport, giving rise to a high Li+ transference number. This GPE extended the electrochemical stability to 4.8 V and improved the stability of interface between the electrolyte and lithium metal anode (reduced overpotential and suppressed lithium dendrites) during storage and repeated lithium plating/stripping cycling. The Li metal anode-based battery employing this GPE exhibits excellent cycling stability and C-rate capability.
More Related Videos
10:27Simultaneous Multi-surface Anodizations and Stair-like Reverse Biases Detachment of Anodic Aluminum Oxides in Sulfuric and Oxalic Acid Electrolyte
Published on: October 5, 2017
08:59Synthesizing a Gel Polymer Electrolyte for Supercapacitors, Assembling a Supercapacitor Using a Coin Cell, and Measuring Gel Electrolyte Performance
Published on: November 30, 2022
Related Concept Videos
Bioavailability Enhancement: Drug Stability Enhancement and GI Retention
Polymers
Electrolyte and Nonelectrolyte Solutions
Electrolytes: van't Hoff Factor
The colligative properties of a solution depend only on the number, not on the identity, of solute species dissolved. The concentration terms in the equations for various colligative properties (freezing point depression, boiling point elevation, osmotic pressure) pertain to all solute species present in the solution. Nonelectrolytes dissolve physically without dissociation or any other accompanying process. Each molecule that dissolves yields one...
¹³C NMR: Distortionless Enhancement by Polarization Transfer (DEPT)
Insensitive Nuclei Enhanced by Polarization Transfer (INEPT)