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Effect of an α-Methyl Substituent on the Dienophile on Diels-Alder endo:exo Selectivity

Olatz Larrañaga1, Abel de Cózar1,2

  • 1Departamento de Química Orgánica I Facultad de Química Universidad del País Vasco and Donostia International Physics Center (DIPC) P. K. 1072 E-20018 San Sebastián-Donostia Spain.

Chemistryopen
|January 18, 2019
PubMed

Keywords:
Diels-Alder reactionsactivation strain modelcycloadditiondensity functional calculationssecond order perturbation energyselectivity

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