Amphiphilicity Regulation of Ag^I Nanoclusters: Self-Assembly and Its Application as a Luminescent Probe

Research on the self-assembly of various amphiphilic molecules is a relatively new research area and of great significance. However, new kinds of metal-nanocluster (NC)-based amphiphilic molecule have rarely been explored. Herein, hydrophobic cation 1-hexadecyl-3-methylimidazolium (C₁₆ mim⁺ ) was chosen to modify hydrophilic (NH₄ )₆ [Ag₆ (mna)₆ ] (Ag₆ -NCs, H₂ mna=2-mercaptonicotinic acid) and Ag₆ @C₁₆ mim-NCs were obtained. Ag₆ @C₁₆ mim-NCs displayed thermotropic liquid crystal and thermofluorescent properties. Moreover, the Ag₆ @C₁₆ mim-NCs exhibits benign amphiphilicity, and it can self-assemble into ordered nanosheets and nanorods through aggregation in water/dimethyl sulfoxide (DMSO) binary solvent mixtures, whereas single Ag₆ -NCs do not. Meanwhile, the Ag₆ @C₁₆ mim-NCs also displays aggregation-induced emission properties owing to the restriction of intramolecular vibrations of the capping ligands. Furthermore, the luminescent aggregates could detect arginine selectively with the detection limit at 28 μm. This study introduces a new kind of metal-NC-based amphiphilic molecule in a supramolecular self-assembly field, and they have potential to be used as optical materials in applied research.