Magnetic orders and origin of exchange bias in Co clusters embedded oxide nanocomposite films

Magnetic nanoparticles embedded oxide semiconductors are interesting candidates for spintronics in view of combining ferromagnetic (FM) and semiconducting properties. In this work, Co-ZnO and Co-V₂O₃ nanocomposite thin films are synthesized by Co ion implantation in crystalline thin films. Magnetic orders vary with the implantation fluence in Co-ZnO, where superparamagnetic (SPM) order appears in the low-fluence films (2  ×  10¹⁶ and 4  ×  10¹⁶ ions cm^-2) and FM order co-exists with the SPM phase in high-fluence films (1  ×  10¹⁷ ions cm^-2). Exchange bias (EB) appears in the high-fluence films, with an EB field of about 100 Oe at 2 K and a blocking temperature of around 100 K. On the other hand, Co-V₂O₃ thin films with an implantation fluence of 3.5  ×  10¹⁶ ions cm^-2 exhibit a clear antiferromagnetic (AFM) coupling at low temperatures without the EB effect. The different magnetic behavior of the Co-implanted films with different Co content leads us to conclude that the observed EB effect in the Co-ZnO films results from the FM/AFM coupling between sizable Co nanoparticles and their CoO/Co₃O₄ surroundings in the (Zn,Co)O matrix. On the other hand, the absence of EB effect in Co-V₂O₃ appears to be due to the small size of the FM Co nanoparticles in spite of an AFM magnetic order. Detailed studies of magnetic orders and EB effect in magnetic nanocomposite semiconductors can pave the way for their application in spintronics.