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Date pits activated carbon for divalent lead ions removal
Rambabu Krishnamoorthy1, Bharath Govindan2, Fawzi Banat2
1Department of Chemical Engineering, School of Civil and Chemical Engineering, VIT University, Katpadi Road, Vellore 632014, India; Department of Chemical Engineering, Khalifa University of Science and Technology, The Petroleum Institute, Al Saada Street, Abu Dhabi 127788, United Arab Emirates.
Date pits were converted into activated carbon for effective lead ion removal. This low-cost material demonstrated high adsorption capacity and reusability, offering a sustainable solution for heavy metal remediation.
Area of Science:
- Environmental Chemistry
- Materials Science
- Adsorption Science
Background:
- Heavy metal contamination, particularly lead (Pb(II)), poses significant environmental and health risks.
- Developing cost-effective and sustainable adsorbents is crucial for efficient water remediation.
Purpose of the Study:
- To prepare and characterize phosphoric acid-impregnated activated carbon from date pits (DPAC).
- To evaluate the efficiency of DPAC for the removal of divalent lead ions from aqueous solutions.
Main Methods:
- Single-step activation of date pits with phosphoric acid to produce DPAC.
- Characterization of DPAC's structural, elemental, chemical, surface, and crystal properties.
- Batch adsorption experiments to study the effects of adsorbent dosage, contact time, pH, temperature, and initial concentration on lead removal.
Main Results:
- DPAC exhibited a maximum Pb(II) adsorption capacity of 101.35 mg/g at pH 6 and 30°C within 30 minutes.
- Adsorption efficiency increased with higher initial lead concentrations and adsorbent dosages.
- Pseudo-second order kinetics and Langmuir isotherm models best described the lead adsorption process.
- DPAC showed good reusability, maintaining <10% efficiency loss after 4 cycles using HCl for regeneration.
Conclusions:
- Date pits serve as a viable, low-cost precursor for producing efficient activated carbon for lead ion removal.
- DPAC demonstrates promising potential as a sustainable adsorbent for mitigating lead pollution in water.
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