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Mg-Mg-bonded compounds with N,N'-dipp-substituted phenanthrene-diamido and o-phenylene-diamino ligands
Meimei Ma1, Huanhuan Wang, Juju Wang
1Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an 710069, China. yangxiaojuan@nwu.edu.cn.
Dalton Transactions (Cambridge, England : 2003)
|January 26, 2019
Abstract:
Two Mg-Mg-bonded compounds were synthesized by using the ligands N,N'-bis(dipp)-phenanthrene-9,10-diimine (L2) and N,N'-bis(dipp)-o-phenylenediamine (H2L3; dipp = 2,6-diisopropylphenyl). These new Mg(i) species were characterized by X-ray diffraction, NMR, UV-Vis and fluorescence spectroscopy, and DFT computations. Their reactions with unsaturated organic molecules were examined.