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Updated: Jan 30, 2026

Characterization of Electrode Materials for Lithium Ion and Sodium Ion Batteries Using Synchrotron Radiation Techniques
Published on: November 11, 2013
Highly crystalline ramsdellite as a cathode material for near-neutral aqueous MnO2/Zn batteries
Ivan Stoševski1, Arman Bonakdarpour, Faye Cuadra
1Department of Chemical and Biological Engineering and the Clean Energy Research Center, University of British Columbia, 2360 East Mall, Vancouver, BC V6T 1Z3, Canada. arman@chbe.ubc.ca dwilkinson@chbe.ubc.ca.
Abstract:
Chemically-prepared MnO2 containing a highly crystalline ramsdellite phase was tested as a cathode material in aqueous Zn-salt (ZnSO4 and Zn(CF3SO3)2) based electrolytes for the first time. This aqueous MnO2/Zn cell has shown excellent performance and reversibility, retaining ≈65% of its initial capacity for more than 1000 cycles. The charge storage mechanism is complex and includes a ramsdellite/tetragonal spinel two-phase reaction.
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