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Published on: May 10, 2013
Structural changes of cassava starch and polylactic acid films submitted to biodegradation process
Margarita Del Rosario Salazar-Sánchez1, Sergio David Campo-Erazo1, Héctor Samuel Villada-Castillo1
1Grupo de Investigación en Ciencia y Tecnología de Interés Agroindustrial, CYTBIA, Departamento de Ingeniería Agroindustrial, Facultad de Ciencias Agrarias, Universidad del Cauca, 190002, Cauca, Colombia.
This study shows that biodegradable films made from polylactic acid (PLA) and starch undergo disintegration and fragmentation during composting. These eco-friendly packaging materials exhibit structural changes throughout the biodegradation process.
Area of Science:
- Materials Science
- Environmental Science
- Polymer Chemistry
Background:
- Polylactic acid (PLA) and starch are utilized in packaging as biodegradable alternatives to petroleum-based products.
- These materials offer environmental benefits due to their eco-friendly nature.
Purpose of the Study:
- To evaluate the structural and surface changes of a cassava starch and PLA composite film during biodegradation.
- To analyze the biodegradation process under standard compost conditions (ISO 4855-2:2007).
Main Methods:
- Extrusion was used to manufacture the composite film.
- Fourier Transform Infrared Spectroscopy (FT-IR) identified functional groups.
- High-Resolution Optical Microscopy (HROM) and Scanning Electron Microscopy (SEM) examined structural and surface alterations.
Main Results:
- The addition of PLA increased the carbonyl index in the composite film.
- Anhydrous malic acid (MA) in PLA/Thermoplastic Starch (TPS) mixtures may further increase the carbonyl index.
- The TPS/PLA composite film exhibited three biodegradation phases: disintegration, fragmentation, and mineralization.
- By week 4, the film showed reduced size, thinning, and fractures, indicating disintegration and fragmentation.
Conclusions:
- The TPS/PLA composite film demonstrated a complete biodegradation cycle under compost conditions.
- Structural and surface analyses confirmed the material's degradation pathway.
- The findings support the use of starch-PLA composites as sustainable packaging solutions.
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