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Investigation of reverse ionic diffusion in forward-osmosis-aided dewatering of microalgae: A molecular dynamics
Jester N Itliong1, Al Rey C Villagracia2, Joaquin Lorenzo V Moreno3
1Physics Department, College of Science, De La Salle University, 2401 Taft Ave., Malate, 1004 Manila, Philippines; Applied Physics Department, Eulogio "Amang" Rodriguez Institute of Science and Technology, Nagtahan, Sampaloc, Manila, Philippines.
Abstract:
This study aimed to investigate the transport mechanisms of ions during forward-osmosis-driven (FO-driven) dewatering of microalgae using molecular dynamics (MD) simulations. The dynamical and structural properties of ions in FO systems of varying NaCl or MgCl2 draw solution (DS) concentrations were calculated and correlated. Results indicate that FO systems with higher DS concentration caused ions to have lower hydration numbers and higher coordination numbers leading to lower diffusion coefficients. The higher hydration number of Mg2+ ions resulted in significantly lower ionic permeability as compared to Na+ ions at all concentrations (p = 0.002). The simulations also revealed that higher DS concentrations led to higher accumulation of ions in the membrane. This study provides insights on the proper selection of DS for FO systems.
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