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Mesoporous ZnCo2O4/rGO nanocomposites enhancing sodium storage
Jie Xu1,2, Bo Yan2, Hirbod Maleki Kheimeh Sari2
1Tianjin International Joint Research Centre of Surface Technology for Energy Storage Materials, Energy & Materials Engineering Centre, College of Physics and Materials Science, Tianjin Normal University, Tianjin 300387, People's Republic of China.
None:
In this study, mesoporous ZnCo2O4/rGO nanocomposites were favorably synthesized via a simple solvothermal technique. As a prospective anode material for sodium-ion batteries, the resulting ZnCo2O4/rGO-II nanocomposite exhibited superior electrochemical sodium storage performance with predominant specific capacity, favorable cyclability and ascendant rate capability. For example, an outstanding discharge capacity of 210.5 mAh g-1 was delivered at a current density of 200 mA g-1. Notably, the nanocomposite could yield a discharge capacity of 101.7 mAh g-1 at a current density of 1000 mA g-1 after 500 loops, which certifies its superior capacity retention and predominant cycling stability. The boosted performance of the anode materials is due to the mutual synergistic effect resulting from a combination of the mesoporous ZnCo2O4 nanospheres and conducting reduced graphene oxide nanosheets.
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