The influence of external electric fields on charge reorganization energy in organic semiconductors

In physics, symmetry in a system means that something in the considered system remains unchanged due to a specific operation to which it is subjected. For example, consider a horizontal square. The square looks the same if its right and left sides are interchanged. Hence, it is symmetric under a right-left interchange.
In calculations of electric fields, symmetry is of great use. For example, while calculating electric fields of continuous charge distributions.
Consider a line element with a...

Atoms generally contain the same number of positively and negatively charged particles, protons, and electrons. Hence, they are electrically neutral. However, the centers of the positive and negative charges do not always coincide. In such a scenario, the electric field of an atom may not be zero.
A separation of the positive and negative charges can lead to a weak, remnant effect of the positive and negative charges. The expectation is that the more the distance between the positive and...

The simplest case of a surface charge distribution is the uniformly charged disk. Calculating its electric field also helps us calculate the electric field of a large plane of charge.
The system's symmetry is in the cylindrical directions across the plane of the charge. As a result, the electric fields created by various surface charge elements nullify each other in the direction parallel to the surface. Thereby, the resulting electric field is perpendicular to the plane. Since the disk is...

The electric potential energy of a test charge in a uniform eclectic field can be generalized to any electric field produced by static charge distribution. Consider a positive test charge in an electric field produced by another static positive charge. If the test charge is moved away from the static charge, then the electric field does the positive work on the test charge, and the electric potential energy of the test charge decreases as it moves away from the static charge. Here the electric...

Gauss's law states that the electric flux through any closed surface equals the net charge enclosed within the surface. This law is beneficial for determining the expressions for the electric field for a particular charge distribution if the electric flux is known.
Consider a non-uniformly charged sphere, for which the density of charge depends only on the distance from a point in space and not on the direction. Such a sphere has a spherically symmetrical charge distribution. Here, the electric...

When an electric field accelerates a free positive charge, it acquires kinetic energy. This process is analogous to an object being accelerated by a gravitational field as if the charge were going down an electrical hill where its electric potential energy is converted into kinetic energy, although, of course, the sources of the forces are very different. The electrostatic or Coulomb force acting on the positive test charge is conservative, which means that the work done on a test charge is...