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Updated: Jan 29, 2026

Neutron Crystallography Data Collection and Processing for Modelling Hydrogen Atoms in Protein Structures
Published on: December 1, 2020
A study of di(amino)stibines with terminal Sb(iii) hydrogen-ligands by X-ray- and neutron-diffraction
Ryan J Schwamm1, Alison J Edwards, Christopher M Fitchett
1School of Chemical and Physical Sciences, Victoria University of Wellington, PO Box 600, Wellington, New Zealand. martyn.coles@vuw.ac.nz.
Abstract:
The bis(amidodimethyl)disiloxane ligands [O{SiMe2NR}2]2- (R = 2,6-Me2C6H3 (Ar') and 2,6-iPr2C6H3 (Ar), abbreviated [NONR]2-, are a stable support for Sb(iii) complexes of general formula Sb(NONR)X (X = Cl, H). The compounds are monomeric in the solid-state, with bidentate N,N'-coordination of the [NONR]2- and terminal chloride/hydrogen-ligands. Sb(NONAr')H was analyzed by single-crystal neutron diffraction, giving the first accurate parameters for the Sb-H bond to an antimony(iii) centre.
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