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Updated: Jan 29, 2026

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Molecular doping: accessing the first carborane-substituted 1,2,3-triphospholanide via insertion of P- into a P-P
Peter Coburger1, Hansjörg Grützmacher, Evamarie Hey-Hawkins
1Leipzig University, Faculty of Chemistry and Mineralogy, Institute of Inorganic Chemistry, Johannisallee 29, D-04103 Leipzig, Germany. hey@uni-leipzig.de.
Abstract:
Insertion of a P- anion into a P-P bond yielding the first carborane-substituted 1,2,3-triphospholanide 1 was achieved by treating a carborane-substitued 1,2-diphosphetane with sodium phosphaethynolate. The triphospholanide 1 can serve as a versatile nucleophilic building block for unprecedent functionalised triphospholanes and carborane-substituted polyphosphanes.
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