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Updated: Jan 29, 2026

Determination of Thermodynamic Properties of Alkaline Earth-liquid Metal Alloys Using the Electromotive Force Technique
Published on: November 3, 2017
Lone-Pair Enhanced Birefringence in an Alkaline-Earth Metal Tin(II) Phosphate BaSn2 (PO4 )2
Yi Yang1,2, Yi Qiu3, Pifu Gong1
1Beijing Center for Crystal R&D, Key Lab of Functional Crystals and Laser Technology, of the Chinese Academy of Sciences, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing, 100190, P. R. China.
Abstract:
The first alkaline-earth metal tin(II) phosphate, BaSn2 (PO4 )2 , has been discovered, which consists of layered structures constructed from strictly alternating [SnO3 ]4- and [PO4 ]3- moieties. This compound is expected to have a large birefringence with Δn≈0.071 at 1064 nm, owing to the presence of stereochemically active lone pair metal cations.
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