Ultraporous Membranes Electrospun from Nonsolvent-Induced Phase-Separated Ternary Systems

Electrospinning of nonsolvent-induced phase-separated ternary (NIPST) systems has gained a lot of interest due to its potential to produce (nano)fibers, which are superficially and internally porous with nanoscale surface roughness. Membranes produced from such systems are expected to have a high specific surface area (SSA; e.g., more than 50 m² g^-1 ), an essential requirement for many of their applications. In spite of their advantages and potential, there are major issues regarding the electrospinning of NIPST systems that are not systematically addressed in the literature. In this paper, the most recent developments are reported and the potential and challenges associated with the electrospinning of NIPST systems are discussed. Furthermore, the essential steps to improve and optimize the electrospinning process of these systems are concisely discussed. By developing a modified time-dependent rheological model, a time range can be defined for NIPST systems as "electrospinnability window," in which fiber functionality and characteristics can be tailored through aging of the systems prior to electrospinning. Some potential post-treatment processes are also proposed based on the results of recent studies to stabilize as-electrospun membranes without damaging their highly porous fibers, which can guarantee their in-service mechanical and morphological stability.