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Enhancing selectivity of cation exchange with anion receptors
Neil J Williams1, Santanu Roy, Campbell O Reynolds
1Oak Ridge National Laboratory, 1 Bethel Valley Road, Oak Ridge, Tennessee 37831-6119, USA. bryantsevv@ornl.gov moyerba@ornl.gov.
Abstract:
We introduce a new supramolecular strategy where an anion receptor modifies the selectivity ligands for cations. This is demonstrated by combining the classic anion receptor calix[4]pyrrole (C4P) and a phenolic ligand, which leads to remarkable enhancement in selectivity for Cs+ over Na+. Crystal structures and molecular simulations confirmed the persistent formation of ion-pair C4P-Cs+-phenolate complexes, while the smaller Na+ ion cannot efficiently interact.
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