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Visible-light-induced metathesis reaction between diselenide and ditelluride
Cheng Liu1, Jiahao Xia, Shaobo Ji
1Key Lab of Organic Optoelectronics and Molecular Engineering, Department of Chemistry, Tsinghua University, Beijing 100084, People's Republic of China. xuhuaping@mail.tsinghua.edu.cn.
Abstract:
The Se-Te bond was prepared by a metathesis reaction between diselenides and ditellurides, which could be manipulated with the presence or absence of visible light. Additionally, the apparent activation energy of the exchange process was measured to be only 28.01 kJ mol-1, explaining the high reactivity and sensitivity to light.
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