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Hair Mechanical Anisotropy-What Does It Tell Us?
Steven Breakspear1, Bernd Noecker1, Crisan Popescu1
1Kao European Research Laboratories, KAO Germany GmbH, Darmstadt D-64297, Germany (S.B., B.N., C.P.).
Abstract:
Hair fibers were examined by atomic force microscopy, nanoindentation. By indenting along (longitudinal) and across (transversal) the fiber, we evaluated the Young's modulus and its dependence on the moisture content (relative humidity) of the environment. The ratio of the two values collected for Young's modulus, at a given relative humidity, is defined as the anisotropy index (IA) of the fiber and the acquired results give the evolution of the index of anisotropy with the relative humidity. The use of the model of composite materials allowed us to relate the anisotropy index to the fiber internal architecture. The evaluation of the results acquired on the components of the fiber, within the frame of this model, ultimately points to a possible micro-structure of exocuticle, hindered under usual circumstances by its heavy cross-linking and only noticeable when the absorbed moisture swells the surrounding network and annuls, in this way, its effect.
Insights
This study reveals how hair fiber
Area of Science:
- Materials Science
- Biophysics
- Textile Science
Background:
- Hair fibers exhibit complex mechanical properties influenced by environmental factors.
- Understanding hair's anisotropic behavior is crucial for material science and cosmetic applications.
Purpose of the Study:
- To investigate the mechanical anisotropy of hair fibers.
- To determine the relationship between anisotropy and moisture content.
- To correlate mechanical anisotropy with hair fiber's internal structure.
Main Methods:
- Atomic force microscopy and nanoindentation were employed to measure mechanical properties.
- Young's modulus was evaluated along (longitudinal) and across (transversal) the hair fiber.
- Anisotropy index (IA) was calculated as the ratio of longitudinal to transversal Young's modulus at varying relative humidity levels.
Main Results:
- The anisotropy index (IA) of hair fibers varies with relative humidity.
- A composite material model was used to link IA to the fiber's internal architecture.
- Results suggest a specific micro-structure of the exocuticle, typically masked by cross-linking, becomes apparent upon moisture absorption.
Conclusions:
- Hair fiber's mechanical anisotropy is humidity-dependent.
- The study provides insights into the hair fiber's micro-structure, particularly the exocuticle.
- Moisture absorption plays a key role in revealing the mechanical properties of the exocuticle.
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