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Updated: Jan 29, 2026

Quantitative and Qualitative Examination of Particle-particle Interactions Using Colloidal Probe Nanoscopy
Published on: July 18, 2014
Which interactions dominate in active colloids?
Benno Liebchen1, Hartmut Löwen1
1Institut für Theoretische Physik II: Weiche Materie, Heinrich-Heine-Universität Düsseldorf, D-40225 Düsseldorf, Germany.
Abstract:
Despite mounting evidence that the same gradients, which active colloids use for swimming, induce important cross-interactions (phoretic interactions), they are still ignored in most many-body descriptions, perhaps to avoid complexity and a zoo of unknown parameters. Here we derive a simple model, which reduces phoretic far-field interactions to a pair-interaction whose strength is mainly controlled by one genuine parameter (swimming speed). The model suggests that phoretic interactions are generically important for autophoretic colloids (unless effective screening of the phoretic fields is strong) and should dominate over hydrodynamic interactions for the typical case of half-coating and moderately nonuniform surface mobilities. Unlike standard minimal models, but in accordance with canonical experiments, our model generically predicts dynamic clustering in active colloids at a low density. This suggests that dynamic clustering can emerge from the interplay of screened phoretic attractions and active diffusion.
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