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Published on: November 15, 2016
Enhanced Circularly Polarized Luminescence from Reorganized Chiral Emitters on the Skeleton of a Zeolitic Imidazolate
Tonghan Zhao1,2, Jianlei Han1, Xue Jin1
1Division of Nanophotonics, CAS Center for Excellence in Nanoscience, CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, National Center for Nanoscience and Technology (NCNST), No.11, ZhongGuanCun BeiYiTiao, Beijing, 100190, P. R. China.
Abstract:
A chiral zeolitic imidazolate framework (ZIF) showing circularly polarized luminescence (CPL) has been successfully constructed by blending binapthyl-derived chiral emitters with ZIF-8 rhombic dodecahedron nanoparticles. This approach solves a major trade-off in CPL-active materials: the large luminescence dissymmetry factor (glum ) always suffers from suppression of luminescence efficiency. Compared to the optical properties of chiral emitters, the obtained chiral ZIF nanomaterials showed an enhanced fluorescence efficiency while the |glum | value is significantly amplified by one order of magnitude. Additionally, enantioselective fluorescence sensing in response to α-hydroxycarboxylic acids has been enhanced in chiral ZIFs. Reorganization and conjunction of chiral emitters to the skeleton of ZIF nanoparticles can greatly improve both the luminescence quantum yield and circularly polarization, which facilitates the design of more efficient chiroptical materials.
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