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Formation of an interlocked double-chain from an organic-inorganic [2]rotaxane
Jesús Ferrando-Soria1, Antonio Fernandez, Iñigo J Vitorica-Yrezabal
1School of Chemistry and Photon Science Institute, The University of Manchester, Oxford Road, Manchester M13 9PL, UK. richard.winpenny@manchester.ac.uk.
Abstract:
Here we show that a structure containing a polymeric interlocking daisy chain is obtained from the reaction of an inorganic-organic [2]rotaxane [HB{CrIII7NiII(μ-F)8(O2CtBu)16}], where B is an organic thread terminated with a bi-pyridyl unit, with an oxo-centered metal carboxylate triangle [FeIII2CoII(μ3-O)(O2CtBu)6(HO2CtBu)3].
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