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A Dual-Stimuli-Responsive Coordination Network Featuring Reversible Wide-Range Luminescence-Tuning Behavior
Zhao-Quan Yao1,2, Jian Xu2, Bo Zou3
1State Key Laboratory of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin, 300071, China.
Abstract:
We herein report a new coordination network that deforms in a smooth and reversible manner under either thermal or pressure stimulation. Concomitantly, the organic fluorophores coordinatively bound to the channel in a face-to-face arrangement respond to this structural deformation by finely adapting their conformation and arrangement. As a result, the material exhibits a remarkable dual-stimuli-responsive luminescence shift across almost the entire visible region: The emission color of the crystal gradually changes from cyan to green upon heating and then to red upon pressure compression. Furthermore, each stage exhibits a linear dependence of both the emission maximum and intensity on the stimulus and is fully reversible.
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