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Excitonic Hamiltonians for Calculating Optical Absorption Spectra and Optoelectronic Properties of Molecular Aggregates and Solids
Published on: May 27, 2020
Slow dynamics and subdiffusion in a non-Hamiltonian system with long-range forces
Romain Bachelard1, Nicola Piovella2, Shamik Gupta3
1Departamento de Fisica, Universidade Federal de São Carlos, Rodovia Washington Luis, km 235, S/n Jardim Guanabara, São Carlos, São Paulo 13565-905, Brazil.
Abstract:
Inspired by one-dimensional light-particle systems, the dynamics of a non-Hamiltonian system with long-range forces is investigated. While the molecular dynamics does not reach an equilibrium state, it may be approximated in the thermodynamic limit by a Vlasov equation that does possess stable stationary solutions. This implies that on a macroscopic scale the molecular dynamics evolves on a slow timescale that diverges with the system size. At the single-particle level, the evolution is driven by incoherent interaction between the particles, which may be effectively modeled by a noise, leading to a Brownian-like dynamics of the momentum. Because this self-generated diffusion process depends on the particle distribution, the associated Fokker-Planck equation is nonlinear, and a subdiffusive behavior of the momentum fluctuations emerges, in agreement with numerics.
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