Related Experiment Video
Updated: Jan 28, 2026
Retrograde Labeling of Retinal Ganglion Cells by Application of Fluoro-Gold on the Surface of Superior Colliculus
Published on: June 17, 2008
Hetero-difunctional Reagent with Superior Flotation Performance to Chalcopyrite and the Associated Surface
Sheng Liu1,2, Lei Xie2, Guangyi Liu1
1College of Chemistry and Chemical Engineering , Central South University , Changsha 410083 , China.
Abstract:
Surface modification by chemical reagents is of profound importance to modulate the surface characteristic and functionality of materials, which has attracted tremendous interest in many research fields and industrial applications, such as froth flotation of minerals. In this work, a new reagent S-[(2-hydroxyamino)-2-oxoethyl]- O-octyl-dithiocarbonate ester (HAOODE) with heterodifunctional ligands was designed and synthesized to improve the flotability of chalcopyrite (CuFeS2). Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy results showed the co-adsorption of heterodifunctional ligands (i.e., dithiocarbonate and hydroxamate groups) of HAOODE on chalcopyrite via Cu(I)-S and Cu(II)-O covalent bonds. The bubble probe atomic force microscopy (AFM) technique was employed to quantitatively measure the air bubble-chalcopyrite interactions with and without the reagent adsorption. AFM force results revealed that the bubble could be more readily attached to flat chalcopyrite after HAOODE treatment under different hydrodynamic conditions because of the enhanced hydrophobic interaction, with the decay length D0 increasing from 0.65 to 1.20 nm. The calculated bubble-particle interaction forces also demonstrated the critical influence of HAOODE treatment, hydrodynamic conditions, and bubble size on the interaction behavior and thin-film drainage process in flotation. In froth flotation, HAOODE exhibited superior recovery for chalcopyrite over pH 3-12 and excellent selectivity for chalcopyrite against pyrite (FeS2) above pH 10.5, as compared to the conventional reagent sodium isobutyl xanthate. This work provides a useful approach to develop effective reagents that could selectively adsorb on desired mineral surfaces through heterodifunctional ligands and to quantitatively evaluate the role of reagent adsorption in the interactions between air bubbles and mineral surfaces at the nano- and microscale. Our results show implications on developing molecular design principles of novel reagents for surface modifications of materials in a wide range of engineering and biological applications.
More Related Videos
Related Concept Videos
01:26EDTA: Auxiliary Complexing Reagents
01:14Acid Halides to Ketones: Gilman Reagent
As shown below, the mechanism proceeds in two steps. First, one of the alkyl groups of the reagent acts as a nucleophile and attacks the acyl carbon of the acid chloride to form a tetrahedral intermediate. This is followed by the reformation of the carbon–oxygen...
03:06Reaction Mechanisms
For instance, the decomposition of ozone appears to follow a mechanism with two steps:
01:14Cranial Bones: Superior and Posterior View
The frontal bone is the single bone that forms the forehead. At its anterior midline, between the eyebrows, there is a slight depression called the glabella. The frontal bone also forms the supraorbital margin of the orbit. Near the middle of this margin is the supraorbital foramen, the opening that provides passage for a sensory nerve to the forehead. The frontal bone is thickened just above each supraorbital margin,...
01:13Preparation of Carboxylic Acids: Carboxylation of Grignard Reagents
01:16Surface Tension and Surface Energy
Consider a beaker filled with liquid. The bulk molecules in the liquid experience equal attractive forces on all sides with the surrounding molecules. However, the surface molecules experience a net attractive force downward due to the bulk molecules. The surface of the liquid behaves like a stretched membrane,...