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A Size-Flexible Organometallic Box for the Encapsulation of Fullerenes
Victor Martínez-Agramunt1, Tobias Eder1,2, Heidar Darmandeh1,3
1Institute of Advanced Materials (INAM), Centro de Innovación en Química Avanzada (ORFEO-CINQA), Universitat Jaume I, Av. Vicente Sos Baynat s/n., Castellón, 12071, Spain.
Abstract:
A palladium-cornered molecular square with four pyrene-bis(imidazolylidene) bridging ligands is reported. This metallo-polygon can encapsulate C60 and C70 . The X-ray diffraction structures of the empty cage as well as the cages complexed with both fullerenes are described. The fullerene encapsulation produces perturbations in the structural parameters of the metallo-square, showing that it can adjust the shape of its cavity to the size of each fullerene.
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