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Variation and distribution of naphthenic acids in Dalian Bay sediment
Shuaijun Zan1, Jing Wang1, Fengbo Wang1
1Key Laboratory of Industrial Ecology and Environmental Engineering, Ministry of Education, School of Environmental Science and Technology, Dalian University of Technology, Dalian 116024, China.
Abstract:
Previous studies that have investigated marine oil pollution have predominantly focused on petroleum hydrocarbons. Naphthenic acids (NAs), in contrast, are toxins that are less well studied. Following the Dalian oil spill accident, monitoring surveys were carried out to investigate NAs in Dalian Bay sediments. Concentrations of NAs were between 14.826 and 34.279 mg kg-1, with acyclic and motorcycle carboxylic acids (43.28% and 35.12%, respectively) being the dominant components. NAs were 10-30 times more abundant than polycyclic aromatic hydrocarbons (PAHs) in the sediment. Further correlation analysis showed the abundance of NAs was highly correlated with total PAH levels (0.705, p < 0.01, n = 24) and total oil (0.485, p < 0.05, n = 24), indicating that NAs may be a potential marker for oil pollution in coastal sediments. The present study may help to expand the scope of marine environmental monitoring and provide guidance for the remediation of marine pollutants.
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