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Updated: Jan 28, 2026

Development and Validation of Chromium Getters for Solid Oxide Fuel Cell Power Systems
Published on: May 26, 2019
Dinitrogen Functionalization Affording Chromium Hydrazido Complex
Jianhao Yin1, Jiapeng Li1, Gao-Xiang Wang1
1Beijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry , Peking University , Beijing 100871 , China.
Abstract:
A series of trinuclear and dinuclear Cr(I)-N2 complexes bearing cyclopentadienyl-phosphine ligands were synthesized and characterized. Further reduction of the Cr(I)-N2 complexes generated anionic Cr(0)-N2 complexes, which could react with Me3SiCl to afford the first chromium hydrazido complex from N2 functionalization. These complexes were found to be effective catalysts for the transformation of N2 into N(SiMe3)3.
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