Polyoxometalate-Based Photochromic Supramolecular Hydrogels with Highly Ordered Spherical and Cylindrical Micellar
1Key Laboratory of Colloid and Interface Chemistry, Ministry of Education, Shandong University, Jinan, 250100, P.R. China.
Abstract:
Polyoxometalates (POMs) have attracted much attention in the field of photochromic materials. However, POM-based photochromic supramolecular hydrogels with high transparency and good photochromic properties are seldom reported. In this work, a homogenous, optically transparent, injectable, and photochromic supramolecular hydrogel was fabricated through the coassembly of ammonium heptamolybdate (Mo7 ) and an imidazolium-based zwitterionic amphiphile (3-(1-hexadecyl-3-imidazolio)propanesulfonate (C16 IPS)). The balance between electrostatic attraction and repulsion of Mo7 clusters and zwitterionic amphiphiles enables them to coassemble into a homogenous and transparent supramolecular hydrogel. By adjusting the molar ratio of C16 IPS/Mo7 , ordered spherical micelle-based hydrogels and aligned wormlike micelle-based hydrogels can be obtained. The incorporation of Mo7 into hydrogels endows these hydrogels with excellent photochromic properties. Specifically, after coassembly with C16 IPS, the photochromic ability of hydrogels is significantly enhanced compared with that of a pure aqueous solution of Mo7 . These hydrogels exhibit great potential applications as photochromic materials for the recording of rewritable information.
Related Concept Videos
Spherical and Cylindrical Capacitor
Conventionally, considering the symmetry, the electric field between the concentric shells of a spherical capacitor is directed radially outward. The magnitude of the field,...
Spherical Coordinates
Polar and Cylindrical Coordinates
Inductance: Solid Cylindrical Conductor
Given the uniform current distribution, the magnetic field Hx and flux density Bx inside the conductor are...
Gravity between Spherical Bodies
This assumption can be proved easily by showing that the expression for gravitational potential energy between a hollow sphere of mass (M) and a point mass (m) is the same as it would be for a pair of extended...
Gauss's Law: Cylindrical Symmetry


