Insights into the CO₂ Stability-Performance Trade-Off of Antimony-Doped SrFeO_3-δ Perovskite Cathode for Solid Oxide...

One major challenge for the further development of solid oxide fuel cells is obtaining high-performance cathode materials with sufficient stability against reactions with CO₂ present in the ambient atmosphere. However, the enhanced stability is often achieved by using material systems exhibiting decreased performance metrics. The phenomena underlying the performance and stability trade-off has not been well understood. This paper uses antimony-doped SrFeO_3-δ as a model material to shed light on the relationship between the structure, stability, and performance of perovskite-structured oxides which are commonly used as cathode materials. X-ray absorption revealed that partial substitution of Fe by Sb leads to a series of changes in the local environment of the iron atom, such as a decrease in the iron oxidation state and increase in the oxygen coordination number. Theoretical calculations show that the structural changes are associated with an increase in both the oxygen vacancy formation energy and metal-oxygen bond energy. The area-specific resistance (ASR) of the perovskite oxide increases with Sb doping, indicating a deterioration of the oxygen reduction activity. Exposure of the materials to CO₂ leads to depressed oxygen desorption and an increased ASR, which becomes less pronounced at higher Sb doping levels. Origin of the stability-performance trade-off is discussed based on the structural parameters.