Mechanochemical synthesis of N-doped porous carbon at room temperature
Mirian Elizabeth Casco1, Sebastian Kirchhoff, Desirée Leistenschneider
1Department of Inorganic Chemistry, Technische Universität Dresden, Bergstrasse 66, 01069, Dresden, Germany. lars.borchardt@tu-dresden.de miriancasco@gmail.com.
Abstract:
We report the one-pot mechanochemical synthesis of N-doped porous carbons at room temperature using a planetary ball mill. The fast reaction (5 minutes) between calcium carbide and cyanuric chloride proceeds in absence of any solvent and displays a facile bottom-up strategy that completely avoids typical thermal carbonization steps and directly yields a N-doped porous carbon containing 16 wt% of nitrogen and exhibiting a surface area of 1080 m2 g-1.
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