Enhanced Gas-Sensing Properties for Trimethylamine at Low Temperature Based on MoO₃/Bi₂Mo₃O₁₂ Hollow Microspheres

Most reported trimethylamine (TMA) sensors have to operate at high temperature, which will consume energy highly. To detect TMA at low temperature, it is necessary to modify the existing materials or develop new materials. In this paper, the sensor based on MoO₃/Bi₂Mo₃O₁₂ hollow microspheres can work at low operating temperature of 170 °C, which were prepared via a simple solvothermal route. The phase and morphology of the product were characterized by an X-ray diffraction meter, a scanning electron microscope and a transmission electron microscope. The surface chemistry of the MoO₃/Bi₂Mo₃O₁₂ sensor was studied with an X-ray photoelectron spectroscope to investigate the TMA sensing mechanism. The MoO₃/Bi₂Mo₃O₁₂ sensor ( S = 25.8) had a higher response to 50 ppm TMA than those of MoO₃ hollow spheres ( S = 10.8) and Bi₂Mo₃O₁₂ sensors ( S = 4.8) at 170 °C. In contrast to the pure MoO₃ and Bi₂Mo₃O₁₂ sensors, the MoO₃/Bi₂Mo₃O₁₂ sensor exhibited an obviously enhanced gas-sensing property for TMA, which might be due to the heterostructure formed between MoO₃ and Bi₂Mo₃O₁₂ and the hollow morphology. It is the first time for MoO₃/Bi₂Mo₃O₁₂ to apply in gas sensors, which might take an important step in the application of MoO₃/Bi₂Mo₃O₁₂ or Bi₂Mo₃O₁₂ in the field of gas sensing.