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Updated: Jan 28, 2026

Using Cyclic Voltammetry, UV-Vis-NIR, and EPR Spectroelectrochemistry to Analyze Organic Compounds
Published on: October 18, 2018
Resolution of mixed dyes by in situ near infrared (NIR) spectroelectrochemistry
David Ibáñez1, Alejandro Pérez-Junquera1, María Begoña González-García1
1Metrohm DropSens S.L., Edificio CEEI, Parque Tecnológico de Asturias, 33428 Llanera, Spain. david.ibanez@metrohm.com pablo.fanjul@metrohm.com.
Abstract:
NIR spectroelectrochemistry has scarcely been used for deconvolving aqueous mixtures due to the water restriction in this spectral range. However, this work offers an interesting approach for the study of mixtures of molecules with similar electrochemical and spectroscopic behaviour by overcoming the limitations of this hybrid technique. As a proof of concept, the resolution of mixtures of two dyes with similar chemical structures demonstrates the usefulness of NIR spectroelectrochemistry.
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