Molybdenum Trioxide (α-MoO₃) Nanoribbons for Ultrasensitive Ammonia (NH₃) Gas Detection: Integrated Experimental and...

A highly-sensitive ammonia (NH₃) gas sensor based on molybdenum trioxide nanoribbons was developed in this study. α-MoO₃ nanoribbons (MoO₃ NRs) were successfully synthesized via a hydrothermal method and systematically characterized using various advanced technologies. Following a simple drop-cast process, a high-performance chemiresistive NH₃ sensor was fabricated through the deposition of a MoO₃ NR sensing film onto Au interdigitated electrodes. At an optimal operation temperature of 450 °C, the MoO₃ nanoribbon-based sensor exhibited an excellent sensitivity (0.72) at NH₃ concentration as low as 50 ppb, a fast response time of 21 s, good stability and reproducibility, and impressive selectivity against the interfering gases such as H₂, NO₂, and O₂. More importantly, the sensor represents a remarkable limit of detection of 280 ppt (calculated based on a signal-to-noise ratio of 3), which makes the as-prepared MoO₃ NR sensor the most sensitive NH₃ sensor in the literature. Moreover, density functional theory (DFT) simulations were employed to understand the adsorption energetics and electronic structures and thus shed light on the fundamentals of sensing performance. The enhanced sensitivity for NH₃ is explicitly discussed and explained by the remarkable band structure modification because of the NH₃ adsorption at the oxygen vacancy site on α-MoO₃ nanoribbons. These results verify that hydrothermally grown MoO₃ nanoribbons are a promising sensing material for enhanced NH₃ gas monitoring.