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Polymorphism in solid materials, once a challenge, is now an opportunity. Controlling molecular packing allows for tailored material properties and novel technological applications.

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Area of Science:

  • Materials Science
  • Solid-State Chemistry
  • Crystallography

Background:

  • Polymorphism, the existence of multiple solid forms of a material, significantly impacts material properties.
  • Historically, controlling polymorphism was difficult, often viewed as a limitation for technological use.
  • Molecular packing dictates material functionality, but precise control remains a challenge.

Purpose of the Study:

  • To highlight polymorphism as a source of enhanced material functionality.
  • To review advancements in controlling and exploiting polymorphism for technological applications.
  • To reframe polymorphism as an enabling technology rather than a problem.

Main Methods:

  • Review of recent progress in polymorphism research.
  • Examination of strategies for controlling molecular packing.
  • Analysis of methods for exploiting metastable states and transitions.

Main Results:

  • Polymorphism offers a pathway to a wider range of material functionalities.
  • Advances enable selection and promotion of specific packing types.
  • Fine-tuning molecular packing allows reproducible control over material properties.

Conclusions:

  • Polymorphism presents significant opportunities for developing advanced materials.
  • Controlling molecular packing is key to unlocking polymorphism's potential.
  • Emerging strategies position polymorphism as a valuable enabling technology.