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Modular Synthesis of Alkylarylazo Compounds via Iron(III)-Catalyzed Olefin Hydroamination
Yan Zhang1, Chenchao Huang1, Xinru Lin1
1Key Laboratory of the Ministry of Education for Advanced Catalysis Materials , Zhejiang Normal University , 688 Yingbin Road , Jinhua 321004 , China.
Abstract:
A novel Fe-catalyzed olefin hydroamination with aryldiazo sulfones for accessing alkylarylazo compounds has been successfully developed. Aryldiazo sulfones are used as radical acceptors, and N-N double bonds will be regenerated when an arene sulfonyl group leaves. The reaction features mild reaction conditions and a broad substrate scope, allowing access to many azo compounds that would be difficult or perhaps impossible to access using other methods.
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