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Atomic Fluorescence Spectroscopy01:29

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Atomic fluorescence spectroscopy (AFS) is an analytical technique that involves the electronic transitions of atoms in a flame, furnace, or plasma being excited by electromagnetic (EM) radiation. When these atoms absorb energy, they become excited and subsequently release energy as they return to their original state. This emitted light, or "fluorescence," is observed at a right angle to the incident beam. Both absorption and emission processes transpire at distinct wavelengths, which...
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Lidar thermometry using two-line atomic fluorescence.

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    This study combines Scheimpflug lidar and two-line atomic fluorescence for remote, spatially resolved flame temperature measurements. The developed technique enables in situ thermometry in challenging industrial settings with limited optical access.

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    Area of Science:

    • Laser-based diagnostics
    • Thermometry
    • Combustion science

    Background:

    • Accurate temperature measurements are crucial for understanding and controlling combustion processes.
    • Traditional methods often struggle with limited optical access in industrial applications.
    • Remote sensing techniques offer a solution for in situ measurements in challenging environments.

    Purpose of the Study:

    • To develop and demonstrate a novel stand-off thermometry technique.
    • To achieve spatially resolved temperature measurements in flames.
    • To assess the feasibility of this technique for industrial applications.

    Main Methods:

    • Integration of Scheimpflug lidar with two-line atomic fluorescence (TLAF).
    • Seeding of indium atoms into the flame for laser excitation.
    • Use of tunable diode lasers at 410.17 nm and 451.12 nm for indium excitation.
    • Collection of fluorescence signals using a line-scan detector and a 2D intensified CCD camera.

    Main Results:

    • Successful 1D and 2D spatially resolved temperature measurements in a flame.
    • Measurements were performed at various heights above a porous-plug burner.
    • Accuracy was primarily limited by spectral overlap and laser power uncertainties.

    Conclusions:

    • The combined Scheimpflug lidar and TLAF technique provides a viable method for remote, in situ thermometry.
    • This approach is particularly valuable for industrial applications with limited optical access.
    • Further refinement can improve accuracy and expand applicability.