Competitive adsorption of gaseous aromatic hydrocarbons in a binary mixture on nanoporous covalent organic polymers...

Covalent-organic polymers (COPs) are recognized for their great potential for treating diverse pollutants via adsorption. In this study, the sorption behavior of benzene and toluene was investigated both individually and in a binary mixture against two types of COPs possessing different -NH₂ functionalities. Namely, the potential of COPs was tested against benzene and toluene in a low inlet partial pressure range (0.5-20 Pa) using carbonyl-incorporated aromatic polymer (CBAP)-1-based diethylenediamine (EDA) [CD] and ethylenetriamine (DETA) [CE]. The maximum adsorption capacity and breakthrough values of both COPs showed dynamic changes with increases in the partial pressures of benzene and toluene. The maximum adsorption capacities (A_max) of benzene (as the sole component in N₂ under atmospheric conditions) on CD and CE were in the range of 24-36 and 33-75 mg g^-1, respectively. In contrast, with benzene and toluene in a binary mixture, the benzene A_max decreased more than two-fold (range of 2.7-15 and 6-39 mg g^-1, respectively) due to competition with toluene for sorption sites. In contrast, the toluene A_max values remained consistent, reflecting its competitive dominance over benzene. The adsorption behavior of the targeted compounds (i.e., benzene and toluene) was explained by fitting the adsorption data by diverse isotherm models (e.g., Langmuir, Freundlich, Elovich, and Dubinin-Radushkevich). The current research would be helpful for acquiring a better understanding of the factors affecting competitive adsorption between different VOCs in relation to a given sorbent and across varying partial pressures.