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Updated: Jan 27, 2026

Fabrication of Spatially Confined Complex Oxides
Published on: July 1, 2013
Selective Aerobic Oxidation of Benzylic Alcohols Catalyzed by a Dicyclopropenylidene-Ag(I) Complex
Roya Mir1, Rozhin Rowshanpour1, Katie Dempsey1
1Department of Chemistry , Brock University , 1812 Sir Isaac Brock Way , St. Catharines , Ontario , Canada L2S 3A1.
Abstract:
The unprecedented synthesis, single-crystal X-ray structure, and first catalytic application of a dicarbene-Ag(I) complex [Ag(BAC)2][CO2CF3] (BAC = bis(diisopropyl)aminocyclopropenylidene) is reported. This novel complex provides a versatile catalytic platform for selective aerobic oxidation of benzylic alcohols to aldehyde or ketone products in high yields. Ease of experimental execution coupled with the use of abundant atmospheric molecular oxygen as an oxidant and low catalyst loading are inherit strengths of these oxidations.
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