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Updated: Jan 27, 2026

Synthesis and Characterization of Functionalized Metal-organic Frameworks
Published on: September 5, 2014
Heterometallic Strategy for Enhancing the Dynamic Separation of C2H2/CO2: A Linear Pentanuclear Cluster-Based
Lianyan Jiang1, Nana Wu1, Qian Li1
1School of Materials Science and Chemical Engineering , Ningbo University , Ningbo 315211 , China.
Abstract:
A family of heterometallic NbU-3-Mn/MIII compounds were synthesized through postsynthetic exchange of MIII ions of a pentanuclear MnII-based metal-organic framework (NbU-3-Mn, where NbU denotes Ningbo University) for enhancing the gas-separation performance. Significantly, NbU-3-Mn/Fe has a C2H2/CO2 separation selectivity similar to that of NbU-3-Mn but exhibits enhanced dynamic separation of C2H2/CO2, which was proven by breakthrough experiments.
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