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Updated: Jan 27, 2026

Synthesis and Characterization of Functionalized Metal-organic Frameworks
Published on: September 5, 2014
Cobalt substitution in a flexible metal-organic framework: modulating a soft paddle-wheel unit for tunable
Jiaxing Zhu1, Junye Chen1, Tianze Qiu1
1Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai, 200438, China. mldeng@fudan.edu.cn yunling@fudan.edu.cn.
Abstract:
Developing feasible ways to achieve tunable gate-opening pressure (Pgo) while minimizing the side effects on the adsorption capacity and enthalpy is greatly desired for flexible MOFs. In this work, we focused on solving this issue by cobalt substitution. We showed the successful modulation of the energy required for the reversible transformation of a soft paddle-wheel so that the whole framework presented a substitution-dependent Pgo for CO2 adsorption.
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