Related Experiment Video
Updated: Jan 27, 2026

Integrating a Triplet-triplet Annihilation Up-conversion System to Enhance Dye-sensitized Solar Cell Response to Sub-bandgap Light
Published on: September 12, 2014
Generation of the Thymine Triplet State by Through-Bond Energy Transfer
Paula Miro1, Miguel Gomez-Mendoza1,2, Germán Sastre1
1Instituto de Tecnología Química, Universitat Politècnica de València-Consejo Superior, de Investigaciones Científicas, Avenida de los Naranjos s/n, 46022, Valencia, Spain.
Abstract:
Benzophenone (BP) and drugs containing the BP chromophore, such as the non-steroidal anti-inflammatory drug ketoprofen, have been widely reported as DNA photosensitizers through triplet-triplet energy transfer (TTET). In the present work, a direct spectroscopic fingerprint for the formation of the thymine triplet (3 Thy*) by through-bond (TB) TTET from 3 BP* has been uncovered. This has been achieved in two new systems that have been designed and synthesized with one BP and one thymine (Thy) covalently linked to the two ends of the rigid skeleton of the natural bile acids cholic and lithocholic acid. The results shown here prove that it is possible to achieve triplet energy transfer to a Thy unit even when the photosensitizer is at a long (nonbonding) distance.
Related Concept Videos
Bond Energies and Bond Lengths
Ionic Bonding and Electron Transfer
Bond Dissociation Energy and Activation Energy
Bonding in Metals
Valence Bond Theory
Valence Bond Theory

