Pressure-induced spin transition and site-selective metallization in CoCl2

Jose A Barreda-Argüeso1, Lucie Nataf2, Fernando Aguado1

  • 1Universidad de Cantabria, MALTA Consolider Team - DCITIMAC, Santander, 39005, Spain.

Scientific Reports
|April 2, 2019
PubMed
Summary

High pressure transforms cobalt chloride (CoCl2) into a metallic state, inducing a spin crossover in cobalt ions. This metallic phase coexists with localized magnetism before full electron delocalization.

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