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Updated: Jan 26, 2026

Triplet Fusion Upconversion Nanocapsule Synthesis
Published on: September 7, 2022
Enhanced Photoelectrochemical Water Splitting through Bismuth Vanadate with a Photon Upconversion Luminescent
Dongho Choi1, Seong Kyung Nam1, Kiwon Kim1
1Department of Chemical and Biomolecular Engineering, Sogang University, Seoul, 04107, Republic of Korea.
Abstract:
As the performance of photoanodes for solar water splitting steadily improves, the extension of the absorption wavelength in the photoanodes is highly necessary to substantially improve the water splitting. We use a luminescent back reflector (LBR) capable of photon upconversion (UC) to improve the light harvesting capabilities of Mo:BiVO4 photoelectrodes. The LBR is prepared by dispersing the organic dye pair meso-tetraphenyltetrabenzoporphine palladium and perylene capable of triplet-triplet annhilation-based UC in a polymer film. The LBR converts the wavelengths of 600-650 nm corresponding to the sub-band gap of Mo:BiVO4 and the wavelengths of 350-450 nm that are not sufficiently absorbed in Mo:BiVO4 to a wavelength that can be absorbed by a Mo:BiVO4 photoelectrode. The LBR improves the water splitting reaction of Mo:BiVO4 photoelectrodes by 17 %, and consequently, the Mo:BiVO4 /LBR exhibits a photocurrent density of 5.25 mA cm-2 at 1.23 V versus the reversible hydrogen electrode. The Mo:BiVO4 /LBR exhibits hydrogen/oxygen evolution corresponding to the increased photocurrent density and long-term operational stability for the water splitting reaction.
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