Sub-3 nm Rh nanoclusters confined within a metal-organic framework for enhanced hydrogen generation
Hui Zhang1, Maolin Huang, Jie Wen
1The Center of New Energy Materials and Technology, College of Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu 610500, China. huizhang@swpu.edu.cn.
Abstract:
Ultrafine sub-3 nm Rh nanoclusters confined within a metal-organic framework (UIO-66) were constructed through a double-solvent host-guest strategy and achieved superior hydrogen generation via ammonia borane hydrolysis compared with Rh nanoclusters dispersed on the exterior walls.
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